Realizing anti-self-discharged lithium-sulfur batteries by using hierarchical porous carbon nanofibers embedded with Fe/Ni-N catalytic sites.

[Display omitted] • The fabricated Fe-Ni-HPCNF has hierarchical porous skeleton and Fe/Ni-N catalytic sites. • Fe-Ni-HPCNF modified cell shows shuttle inhibition and kinetics promotion. • It sheds new light for the design of anti-self-discharged lithium-sulfur batteries. Lithium-sulfur (Li-S) batteries are featured with high gravimetric energy density, yet their commercial application is significantly deteriorated with the severe self-discharging resulted from the polysulfides shuttle and sluggish electrochemical kinetics. Here, a hierarchical porous carbon nanofibers implanted with Fe/Ni-N (denoted as Fe-Ni-HPCNF) catalytic sites are prepared and used as a kinetics booster toward anti-self-discharged Li-S batteries. In this design, the Fe-Ni-HPCNF possesses interconnected porous skeleton and abundant exposed active sites, enabling fast Li-ion conduction, excellent shuttle inhibition and catalytic ability for polysulfides' conversion. Combined with these advantages, this cell with the Fe-Ni-HPCNF equipped separator exhibits an ultralow self-discharged rate of 4.9% after resting for one week. Moreover, the modified batteries deliver a superior rate performance (783.3 mAh g−1 at 4.0 C) and an outstanding cycling life (over 700 cycles with 0.057% attenuation rate at 1.0 C). This work may guide the advanced design of anti-self-discharged Li-S batteries. [ABSTRACT FROM AUTHOR]