Experimental investigation on sulfur transformation during coal steam gasification with Ca-based absorbent.

[Display omitted] • The transformation paths of sulfur during coal steam gasification with CaO addition was identified. • The release characteristics of H 2 S were monitored online. • Factors which might affect the sulfur transformation were analyzed in detail. To investigate the effects of temperature, Ca-based absorbent (CaO) and atmosphere on the sulfur transformation characteristics in coal steam gasification, experiments were conducted in a fixed-bed reactor. As temperature increased from 600 °C to 750 °C, H 2 S-S (sulfur in H 2 S) was elevated by 21.86% and absorbent-S decreased by 7.66%. More gaseous sulfur was captured by organic groups to form organic sulfur in char at higher temperature. CaO promoted the sulfur conversion, and played the role of gaseous sulfur absorbent at the same time, and showed an ability of organic sulfur removal. CaO slowed down the H 2 S release by reacting with it to form CaS, resulting in that the peak concentration of H 2 S without CaO reached 1026.7 ppm, which decreased to 426.3 ppm with CaO. The increase in Ca/C promoted the sulfur conversion slightly and reduced the sulfate content in char. Compared with inert atmosphere, H 2 S-S in the steam atmosphere increased by 35.07%, while absorbent-S decreased by 23.42%. The solid–solid reaction mechanism is more suitable for the sulfate transformation in inert atmosphere, while the gas–solid reaction mechanism is more suitable in steam atmosphere. The sulfur conversion in inert atmosphere was lower, but sulfate had a higher decomposition rate. [ABSTRACT FROM AUTHOR]