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Dibenzyl-(1 S *,2 S *)-2,3-dihydro-1 H -indene-1,2-dicarboxylate.
- Source :
-
Molbank . Mar2023, Vol. 2023 Issue 1, pM1586. 5p. - Publication Year :
- 2023
-
Abstract
- The synthesis of dibenzyl-(1S*,2S*)-2,3-dihydro-1H-indene-1,2-dicarboxylate has been realized through a diastereospecific bis-alkoxycarbonylation reaction, which starts from the cheap and easily available 1H-indene, benzyl alcohol, and carbon monoxide. The catalyst is formed in situ by mixing Pd(TFA)2, the ligand N2,N3-bis(2,6-dimethylphenyl)butane-2,3-diimine, p-benzoquinone is used as an oxidant, and benzyl alcohol acts both as a nucleophile and as the main solvent. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14228599
- Volume :
- 2023
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Molbank
- Publication Type :
- Academic Journal
- Accession number :
- 162812527
- Full Text :
- https://doi.org/10.3390/M1586