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Low‐Temperature Potassium Batteries Enabled by Electric and Thermal Field Regulation.
- Source :
-
Angewandte Chemie . 4/11/2023, Vol. 135 Issue 16, p1-8. 8p. - Publication Year :
- 2023
-
Abstract
- Recharging batteries operate at sub‐zero temperature is usually limited by the slow ion diffusion and uneven charge distribution at low temperature. Here, we report a strategy to regulate electric field and thermal field simultaneously, creating a fast and uniform deposition surroundings for potassium ion in potassium metal batteries (PMBs). This regulation is achieved by using a highly ordered 1D nanoarray electrode which provides a dense and flat surface for uniforming the electric field and high thermal conductivity for reducing the temperature fluctuation. Consequently, this electrode could achieve high‐areal capacity of 10 mAh cm−2. Besides, the dependence of potassium nucleation on temperature is unveiled. Furthermore, a full‐cell could steady operate with over 80 % of its room‐temperature capacity at −20 °C. Those respectable performances demonstrate that this strategy is valid, potentially providing guidelines for the rational design of advanced electrodes toward PMBs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 135
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 162877922
- Full Text :
- https://doi.org/10.1002/ange.202300016