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Selective multi-electron aggregation at a hypervalent iodine center by sequential disproportionation.
- Source :
-
Chemical Communications . 4/14/2023, Vol. 59 Issue 29, p4308-4311. 4p. - Publication Year :
- 2023
-
Abstract
- We demonstrate that sequential disproportionation reactions can enable selective aggregation of two- or four electron–holes at a hypervalent iodine center. Disproportionation of an anodically generated iodanyl radical affords an iodosylbenzene derivative. Subsequent iodosylbenzene disproportionation can be triggered to provide access to an iodoxybenzene. These results demonstrate multielectron oxidation at the one-electron potential by selective and sequential disproportionation chemistry. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DISPROPORTIONATION (Chemistry)
*IODINE
*HYPERVALENCE (Theoretical chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 29
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 162938045
- Full Text :
- https://doi.org/10.1039/d3cc00549f