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Bean pod-like hollow Zn2SnO4/SnO2 heterostructures in N-doped carbon nanofibers as anode material for high performance lithium storage.
- Source :
-
Journal of Alloys & Compounds . Jul2023, Vol. 948, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- Tin-based composites have been extensively investigated as a potential anode for high performance lithium-ion batteries (LIBs) up until this point. However, because of extreme volume expansion and crystal crushing, the researchers have consistently experienced a loss in capacity during lithiation and alloying. To buffer the volume change and achieve superior rate capability, the hollow cube-shaped Zn 2 SnO 4 /SnO 2 which is wrapped with one-dimensional N-doped carbon nanofibers (CNFs) is prepared. The composites display a delicate bean pod-like heterointerface structure, in which the built-in electric field between Zn 2 SnO 4 and SnO 2 can help to speed up the transportation of Li-ions during lithiation and delithiation processes. Additionally, the abundant Zn 2 SnO 4 /SnO 2 heterointerfaces expose more active sites and make it easier for electrolyte and Li-ion to penetrate. And the N-doped carbon skeleton outside of the Zn 2 SnO 4 /SnO 2 can help to keep the structural integrity and suppress volume expansion during cycling. As expected, the as-prepared samples exhibit excellent rate performance and a very high ultimate discharge capacity of 765.9 mA h g−1 after 500 cycles at current density of 1.0 A g−1. Furthermore, a full-cell with a prelithiated Zn 2 SnO 4 /SnO 2 @CNFs-600 anode and a LiFePO 4 cathode also displays superior rate and cycling performance. This work highlights the significance of chemical heterointerface engineering in the design of high-performance electrodes for LIBs. • Bean pod-like heterointerface Zn 2 SnO 4 /SnO 2 @CNFs obtained by electrostatic spinning and in-situ pyrolysis. • High reversible capacity (754.9 mA h g−1 at 1.0 A g−1 for 500 cycles) and excellent stability. • Nitrogen-doped carbon nanofibers and heterostructures with synergistic effects. • The in-situ generated Zn 2 SnO 4 /SnO 2 heterointerface facilitates electrolyte infiltration and Li+ storage. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 948
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 162977280
- Full Text :
- https://doi.org/10.1016/j.jallcom.2023.169579