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Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant.
- Source :
-
Chemical Communications . 4/30/2023, Vol. 59 Issue 34, p5067-5070. 4p. - Publication Year :
- 2023
-
Abstract
- We have introduced a Friedel–Crafts alkylation strategy of a Ni-salphen complex as derived from 2-hydroxy-5-methoxybenzaldehyde, an isomer of biomass derived vanillin, to construct a Ni-salphen based porous organic polymer (Ni@T-POP). The X-ray absorption spectroscopy (XAS) analysis revealed the existence of Ni–N2O2 core sites in the Ni@T-POP framework, which demonstrates unprecedented catalytic efficiency towards oxidative decontamination of sulfur mustards (HD's) compared to its complex precursor. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 163312054
- Full Text :
- https://doi.org/10.1039/d3cc00349c