High energy storage performance in Sr0.64Bi0.18Na0.18TiO3-ZnO hybrid solid solution ceramics.

Ceramic-based capacitors with excellent recoverable energy storage density (Wrec) and efficiency (η) are greatly desired for pulsed capacitors but challenge as well. In this work, the high energy storage performance with an Wrec of 5.1 J/cm3, an η of 93.4%, and an ultrafast discharge–charge speed t0.9 of 72 ns is achieved in unusual interstitial and substitutional hybrid solid solution of Sr0.64Bi0.18Na0.18TiO3-ZnO (SBNT-Zn), in which two Zn2+ ions occupy one A-site, while one Zn2+ ion occupies one B-site of ABO3 perovskite lattice simultaneously. The addition of Zn2+ increases lattice distortion and breaks long-range ferroelectric order, resulting in more highly dynamic polar nanoregions, higher relaxation behaviors as well as larger polarization (ΔP). Moreover, the extraordinary hybrid solid solution configuration enhances the bandgap of SBNT-Zn and ZnO as a sintering aid refines grain size, both help to enhance electric breakdown strength. This work affirms the feasibility and reliability of forming a hybrid solid solution to develop high-performance ferroelectric materials. [ABSTRACT FROM AUTHOR]