Co-transport of biochar nanoparticles (BC NPs) and rare earth elements (REEs) in water-saturated porous media: New insights into REE fractionation.

The present study investigated the co-transport behavior of three REEs3+ (La3+, Gd3+, and Yb3+) with and without biochar nanoparticles (BC NPs) in water-saturated porous media. The presence of REEs3+ enhanced the retention of BC NPs in quartz sand (QS) due to decreased electrostatic repulsion between BC NPs and QS, enhanced aggregation of BC NPs, and the contribution of straining. The distribution coefficients (K D) in packed columns in the co-transport of BC NPs and three REEs3+ were much smaller than in batch experiments due to the different hydrodynamic conditions. In addition, we, for the first time, found that REE fractionation in the solid-liquid phase occurred during the co-transport of REEs3+ in the presence and absence of BC NPs. Note that the REE fractionation during the co-transport, which is helpful for the tracing application during earth surface processes, was driven by the interaction of REEs3+ with QS and BC NPs. This study elucidates novel insights into the fate of BC NPs and REEs3+ in porous media and indicates that (i) mutual effects between BC NPs and REE3+ should be considered when BC was applied to REE contaminated aquatic and soil systems; and (ii) REE fractionation provides a useful tool for identifying the sources of coexisting substances. [Display omitted] • REE fractionation occurs during the co-transport with and without BC NPs. • Both quartz sand and BC NPs result in more Yb3+ enrichment during the co-transport. • REE fractionation in their co-transport is subject to the lanthanide contraction. • Mutual effects between BC NPs and REEs3+ are found in their co-transport. • Batch tests overestimate the adsorption of REEs3+ by BC NPs compared to column data. [ABSTRACT FROM AUTHOR]