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Electron paramagnetic resonance studies of the high-spin molecule Cr10(OMe)20(O2CCMe3)10.

Authors :
Sharmin, Sonia
Ardavan, Arzhang
Blundell, Stephen J.
Coldea, Amalia I.
McInnes, Eric J. L.
Low, David
Source :
Applied Physics Letters. 1/17/2005, Vol. 86 Issue 3, p032507. 3p. 1 Diagram, 4 Graphs.
Publication Year :
2005

Abstract

We report millimeter-wave magneto-optical measurements on the high-spin molecule, Cr10(OMe)20(O2CCMe3)10. The dependence of the electron paramagnetic resonance as a function of orientation and temperature demonstrates that this compound behaves as a single molecule magnet, and exhibits one of the smallest zero-field splittings (D=-0.045±0.004 K) yet reported for such a system. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00036951
Volume :
86
Issue :
3
Database :
Academic Search Index
Journal :
Applied Physics Letters
Publication Type :
Academic Journal
Accession number :
16345292
Full Text :
https://doi.org/10.1063/1.1851613