Shock-induced reactive molecular dynamics simulation in sodium aluminosilicate hydrate: Wave propagation, mechanical response, and structural deformation.

• Reactive molecular dynamics is utilized to simulate shock compression in sodium aluminosilicate hydrate gels. • Distinctive shock-wave induced mechanical response stages are determined. • The relationships between shock-induced wave speed and impact velocity are demonstrated. • Structural deformation mechanisms are proposed in disparate mechanical response stages. Sodium aluminosilicate hydrate (N-A-S-H) gels have gained attention due to their potential use as components of geopolymers to improve structural and mechanical properties. In this study, we investigated the propagation of shock waves in N-A-S-H gels subjected to impact velocities (U p) ranging from 0.1 to 3.0 km/s, as well as the resulting mechanical responses and structural deformations. Our results showed that when U p <0.4 km/s, only one elastic wave existed, and the Hugoniot elastic limit was estimated to be 4.1 GPa. Above this limit, a two-wave structure formed. The elastic and elastoplastic deformation mechanisms involved initial compaction and densification of the N-A-S-H gel structure, followed by bond angle bending. The Hugoniot U s - U p relationship was found to be linear in the elastoplastic region, with a linear parameter λ of approximately 2.75. These new atomistic insights into the shock compression of N-A-S-H gels will provide valuable guidance for future studies. [ABSTRACT FROM AUTHOR]