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VC@C composites derived from polyoxovanadate assisted by dicyandiamide as low-cost platinum-free counter electrode electrocatalyst for dye-sensitized solar cells.
- Source :
-
International Journal of Hydrogen Energy . Jun2023, Vol. 48 Issue 49, p18634-18643. 10p. - Publication Year :
- 2023
-
Abstract
- Vanadium-based carbides have been applied as Pt-free counter electrodes (CEs) electro-catalysts for dye-sensitized solar cells (DSSCs) due to the advantages of earth-abundant reserves, diverse composition, ease modification, and low cost. Herein, the polyoxovanadate (NH 4) 2 V 6 O 16 as V source assisted by dicyandiamide (C 2 H 4 N 4) as C source via simply physical mixing by ball-milling to assemble VC@C precursors. And then, five different VC@C composites derived from precursors with mass ratios of dicyandiamide to polyoxovanadate of 5:1, 10:1, 15:1, 20:1 and 25:1 at 900 °C, and further achieved power conversion efficiencies (PCEs) of 5.4%, 5.6%, 6.6%, 6.2% and 5.1% as CEs for regenerate traditional I 3 −/I− couple in the encapsulated DSSCs, respectively. The effects of different mass ratio of dicyandiamide on the catalytic performances of VC@C composite CEs were also assessed using cyclic voltammetry, electrochemical impedance spectroscopy and Tafel polarization experiments. The photocurrent-photovoltage (J - V) results indicated that VC@C composites CEs had high conductivity and rich number of active sites, which indicated that VC@C composites could be a cost-effective and high-performance alternative Pt-based CEs catalyst for DSSCs. • The pyrolysis of polyoxovanadates assisted by C 2 H 4 N 4 to derive VC@C composites. • VC@C composites were designed as counter electrode by the mass ratio optimized. • The obtained VC@C-3 has high conductivity and rich active sites. • The DSSCs with VC@C-3 composites CEs had the highest PCE of 6.6%. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 48
- Issue :
- 49
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 163820845
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2023.01.294