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Light-mediated sulfonyl-iodination of ynamides and internal alkynes.
- Source :
-
Chemical Communications . 5/28/2023, Vol. 59 Issue 43, p6584-6587. 4p. - Publication Year :
- 2023
-
Abstract
- We synthesized tetrasubstituted olefins regioselectively and stereoselectively from ynamides and internal alkynes with sulfonyl iodides under blue LEDs in few minutes. The key features are being metal-free, easy to handle, simple, broad in scope, and environmentally friendly. Furthermore, a gram-scale experiment was conducted, and the synthesized corresponding sulfonyl-iodinated products were smoothly altered into various other products. [ABSTRACT FROM AUTHOR]
- Subjects :
- *YNAMIDES
*ALKYNES
*ALKENES
*IODIDES
*SONOGASHIRA reaction
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 43
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 163909194
- Full Text :
- https://doi.org/10.1039/d3cc00842h