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Stereoselective synthesis of monofluoroalkenyl silanes via copper-catalyzed decarboxylative silylation of α-fluoroacrylic acids.
- Source :
-
Tetrahedron . Jun2023, Vol. 139, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- A copper-catalyzed decarboxylative/dehydrogenative cross-coupling reaction of α-fluoroacrylic acids with silanes has been developed. A wide range of α-fluoroacrylic acids containing many critical functional groups reacted smoothly, giving desired monofluoroalkenyl silanes with excellent E -stereoselectivity. This protocol provides a convenient strategy for accessing monofluoroalkenyl silanes, without using expensive iridium catalysts to prepare the silylborane and without the need for harsh conditions. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 139
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 163944532
- Full Text :
- https://doi.org/10.1016/j.tet.2023.133446