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In-situ compensation for thermal strain by phase transformation strain in all-inorganic perovskite solar cells.
- Source :
-
Chemical Engineering Journal . Aug2023, Vol. 469, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- [Display omitted] • Residual strain is released via in-situ compensation by phase transformation strain. • The addition of DMSO optimizes PbBr 2 crystallization kinetics and film morphology. • CsPbBr 3 film quality is improved with 2.91 μm-grain size and reduced defect density. • The unsealed device achieves a best PCE of 10.11% and high moisture-heat stability. The presence of defects and residual tensile strain in perovskites has a significant and deleterious impact on the efficiency and stability of all-inorganic perovskite solar cells (PSCs). Here, dimethyl sulfoxide (DMSO) with strong polarity and high boiling point is introduced into the PbBr 2 precursor to delay the crystallization of PbBr 2 , leading to the formation of high-quality PbBr 2 films by delaying the solution reaching supersaturation. The formation of PbBr 2 (DMSO) adduct facilitates the complete reaction of PbBr 2 with CsBr via intramolecular exchange, thus preventing the formation of impurity phases such as CsPb 2 Br 5. As a result, the defect density of CsPbBr 3 films decreased by 33% due to the improved phase purity, thicker films, larger grain sizes, and reduced grain boundaries. The small porosity of PbBr 2 film combined with a more complete phase-conversion process results in an expanded perovskite film that experiences compressive strain, effectively compensating for the tensile strain generated during annealing and thereby achieving the goal of strain relaxation. The optimized DMSO-based device, which exhibits compressive strain and minimal defects, achieves a remarkable efficiency of 10.11% with an open-circuit voltage of up to 1.611 V. Additionally, the unencapsulated PSC demonstrates excellent stability under 80% relative humidity and 80 °C over 30 days. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 469
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 164582517
- Full Text :
- https://doi.org/10.1016/j.cej.2023.143881