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A five-stranded heterometallic helicate.

Authors :
Sudan, Sylvain
Fadaei-Tirani, Farzaneh
Severin, Kay
Source :
Chemical Communications. 7/7/2023, Vol. 59 Issue 53, p8258-8261. 4p.
Publication Year :
2023

Abstract

A penta-stranded helicate was obtained by combining [Pd(CH3CN)4](BF4)2 with La(NO3)3 and a polydentate ligand. The helicate displays low symmetry, both in solution and in the solid state. A dynamic interconversion between the penta-stranded helicate and a symmetrical, four-stranded helicate was achieved by adjustment of the metal-to-ligand ratio. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*SOLID solutions
*SYMMETRY

Details

Language :
English
ISSN :
13597345
Volume :
59
Issue :
53
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
164654905
Full Text :
https://doi.org/10.1039/d3cc02045b