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Influence of lattice vibrations and phonon interactions on the ion transport properties of grain boundary tailored Li1.3Al0.3Ti1.7(PO4)3 solid-state electrolyte ceramics.
- Source :
-
Journal of Applied Physics . 6/28/2023, Vol. 133 Issue 24, p1-16. 16p. - Publication Year :
- 2023
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Abstract
- Lithium ions shuttle between electrodes through the ceramic solid electrolyte across the boundary regions in a solid-state Li-ion battery. This work demonstrates how phonon vibrations get altered by sintering conditions, and grain boundaries (GBs) could be useful in enhancing the ionic conductivity of solid electrolytes. GB engineered Li1.3Al0.3Ti1.7(PO4)3 (LATP) ceramics are prepared using a sol-gel process and performed sintering under different conditions, viz., spark plasma sintering (SPS) and conventional isothermal sintering (CIS). The former exhibits GB regions with amorphous characteristics, whereas the latter shows a sharp boundary between crystalline grains. LATP-SPS ceramic shows two orders of higher ionic conductivity (σ = 1.02 × 10−5 S/cm at 300 K and 100 Hz) than LATP-CIS. We investigate the interrelation between lattice vibration and lithium-ion migration by monitoring the changes in vibrational mode characteristics of LATP ceramics through temperature-dependent Raman spectroscopy. Raman modes of LATP-SPS exhibit a higher Raman shift (∼2 cm−1 at 123 K) due to increased defects, preferentially from grain boundary regions, compared to the LATP-CIS pellet. Most of the vibrational modes undergo a red shift (∼10 cm−1) with increasing temperature, except for the O–P–O bending mode [A1g(3)], which exhibits a blue shift (∼3 cm−1). These observations correlate with interstitial ionic migration in the LATP framework. Force constant of the observed Raman modes suggests that lithium-ion migration is assisted significantly by dynamic structural changes of the (PO4)3− sublattice. Anharmonicities observed from temperature-dependent changes in Raman profiles are explained using three-phonon and four-phonon scattering processes, which lower the migration barrier and, hence, contribute to higher ionic conductivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00218979
- Volume :
- 133
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Journal of Applied Physics
- Publication Type :
- Academic Journal
- Accession number :
- 164666020
- Full Text :
- https://doi.org/10.1063/5.0147635