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MSA Distinguished Lecturer Series Correlations between cathodoluminescence intensity and aluminum concentration in low-temperature hydrothermal quartz.
- Source :
-
American Mineralogist . Jul2023, Vol. 108 Issue 7, p1224-1231. 8p. - Publication Year :
- 2023
-
Abstract
- Quartz cathodoluminescence (CL) images are commonly combined with trace element concentrations to decipher complex histories of hydrothermal systems. However, the correlations between aluminum content and CL zoning of low-temperature hydrothermal quartz and their genesis remain controversial. In this contribution, a multiparametric study was carried out on CL-aluminum zoning of low-temperature hydrothermal quartz (<350 °C) from the Shihu and Rushan quartz-vein type Au deposits in the North China Craton. The results show that aluminum concentration correlates negatively with CL intensity in quartz from the Shihu Au deposit. CL-dark quartz zoning has significant Al concentrations as well as detectable Al-H bonds. However, in the Rushan Au deposit, the correlation is positive, and aluminum is enriched in the CL-bright quartz zoning. The Al content is positively correlated with K content with r2 = 0.769. Combined with the electron backscatter diffraction (EBSD), X-ray single crystal diffraction (XRD), and transmission electron microscope (TEM) data, we infer that the genesis of CL zoning in the low-temperature hydrothermal quartz is closely related to Al3+-H+ and Al3+-K+ concentrations. The Al3+-K+ may act as the CL-activator, while the Al3+-H+ may act as the CL-dampener. Where Al3+-Si4+ substitution is charge balanced by hydrogen, the intensity of CL response decreases; where Al3+-Si4+ substitution is charge balanced by potassium, the intensity of CL response increases. The correlations between CL intensity and aluminum concentration in the low-temperature hydrothermal quartz reflect pH fluctuations of hydrothermal system. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CATHODOLUMINESCENCE
*TRANSMISSION electron microscopes
*ALUMINUM
*GOLD ores
Subjects
Details
- Language :
- English
- ISSN :
- 0003004X
- Volume :
- 108
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- American Mineralogist
- Publication Type :
- Academic Journal
- Accession number :
- 164870768
- Full Text :
- https://doi.org/10.2138/am-2022-8471