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Stereoselective synthesis of (+)-boronolide
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Mar2005, Vol. 46 Issue 12, p2129-2131. 3p. - Publication Year :
- 2005
-
Abstract
- Abstract: An efficient enantio- and stereocontrolled total synthesis of (+)-boronolide from valeraldehyde is described. The key steps include a Sharpless asymmetric dihydroxylation, a chelation controlled Grignard reaction followed by Sharpless asymmetric epoxidation and a ring closing metathesis. [Copyright &y& Elsevier]
- Subjects :
- *METATHESIS reactions
*ENANTIOMERS
*OPTICAL isomers
*CHIRALITY
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 46
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 16596485
- Full Text :
- https://doi.org/10.1016/j.tetlet.2005.01.120