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Catalytic Coupling of Haloolefins with Anilides.
- Source :
-
Journal of the American Chemical Society . 3/30/2005, Vol. 127 Issue 12, p4156-4157. 2p. - Publication Year :
- 2005
-
Abstract
- The article focuses on catalytic coupling of haloolefins with anilides. Extensive synthetic methodology has been developed based on oxidative addition reactions of C-X bonds (X = halogen, hetero-atom). Catalytic C-C bond-forming reactions arising from C-H bond activations are less common despite the wider availability, price, and environmental advantages of the starting hydrocarbons compared to functionalized compounds. The focus of many recent studies has moved from investigations of the C-H bond activation step to the application of these findings in catalytic processes. An example illustrating the catalytic C-C bond-forming reaction is palladium-catalyzed oxidative coupling of benzene derivatives with alkenes bearing electron-withdrawing groups.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 16617753
- Full Text :
- https://doi.org/10.1021/ja050366h