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Efficient removal of dyes from water by zirconium-based metal-organic cages with varying functional groups.
- Source :
-
Journal of Molecular Structure . Nov2023, Vol. 1291, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- • A series of Zr-MOCs with different functional groups were synthesized. • Zr-MOCs exhibit efficient adsorption for MO and RhB. • ZrT-1 exhibits the most excellent adsorption ability for MO and RhB. • The mechanism of dye adsorption was investigated in detail. The adsorption of organic dyes from wastewater is an efficient approach to reduce dye pollution for water resources and land. Herein, a series of zirconium-based metal-organic cages (Zr-MOCs) with different functional groups, ZrT-1, ZrT-1-Br, ZrT-1-NH 2 and ZrT-1-OH, were synthesized by solvothermal that can be applied to remove methyl orange (MO) and rhodamine B (RhB). The adsorption kinetics of Zr-MOCs was fitted well by pseudo-second-order. ZrT-1 exhibits the most excellent adsorption ability for MO and RhB compared with the other Zr-MOCs due to the highest pore volume. Interestingly, Zr-MOCs can remove both anionic dye (MO) and cationic dye (RhB) due to the synergistic interplay between pore volume, electrostatic interaction, π-π interaction and hydrogen bonding. The adsorption behaviors of MO and RhB on ZrT-1 are suitable to the Langmuir model that belong to the monolayer adsorption. The maximum adsorption capacities for MO and RhB towards ZrT-1 are 190 mg/g and 227 mg/g at 25 °C, pH=7 and the initial dye concentration of 80 mg/L, respectively. A series of zirconium-based metal-organic cages with different functional groups were synthesized and exhibit efficient adsorption for MO and RhB. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222860
- Volume :
- 1291
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Structure
- Publication Type :
- Academic Journal
- Accession number :
- 166740015
- Full Text :
- https://doi.org/10.1016/j.molstruc.2023.136018