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Ru(phen)3Cl2‐Catalyzed Chlorotrifluoromethylation of Unactivated Alkenes.
- Source :
-
ChemistryOpen . Jul2023, Vol. 12 Issue 7, p1-5. 5p. - Publication Year :
- 2023
-
Abstract
- A novel Ru(phen)3Cl2‐catalyzed free‐radical chlorotrifluoromethylation reaction of unactivated olefins was investigated. Substituted 8‐aminoquinoline‐derived inert enamides were reacted with the Togni regent to afford a broad range of Cl‐containing trifluoromethyl derivatives in good yields. The reaction proceeded at 90 °C and experimental result shows that the chlorine source of the products originated from LiCl. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21911363
- Volume :
- 12
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- ChemistryOpen
- Publication Type :
- Academic Journal
- Accession number :
- 167301971
- Full Text :
- https://doi.org/10.1002/open.202300068