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Sodium Dialkyl-amidozincates: Alkyl or Amido Bases? An Experimental and Theoretical Case Study.
- Source :
-
Journal of the American Chemical Society . 5/4/2005, Vol. 127 Issue 17, p6184-6185. 2p. - Publication Year :
- 2005
-
Abstract
- This article reports that alkali metal zincates are fast establishing themselves as a new vanguard class of organozinc reagent, to add to the old guard of organozinc halides and diorganozincs. Among the best developed alkali metal zincates are homoleptic triorganozincates and heteroleptic diorgano-amidozincates. In the latter category, lithium di-tert-butyltetramethylpiperidinozincate is receiving special attention in view of its high chemo-/regioselectivity in deprotonative reactions of, for example, functionalized aromatics and functionalized heteroaromatics.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 16964632
- Full Text :
- https://doi.org/10.1021/ja050860l