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Highly efficient arylation of malonates with diaryliodonium salts.

Authors :
Chang Ho Oh
Joo Sung Kim
Source :
Journal of Organic Chemistry. 02/19/99, Vol. 64 Issue 4, p1338. 3p. 10 Diagrams, 3 Charts.
Publication Year :
1999

Abstract

Presents the study on the arylation of malonates with diaryliodonium salts. Reaction of diethyl methylmalonate with diphenyliodonium tetrafluoroborate; Effect of the palladium catalyst in the desired arylation; Preparation of (2,4,6-trimethoxyphenyl)phenyliodonium salt and its reaction with various enolates.

Subjects

Subjects :
*MALONIC acid
*ARYLATION

Details

Language :
English
ISSN :
00223263
Volume :
64
Issue :
4
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
1698945
Full Text :
https://doi.org/10.1021/jo981065b