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Controlling the electronic structure of Fe-MOF electrocatalyst for enhanced water splitting and urea oxidation: A plasma-assisted approach.
- Source :
-
Journal of Colloid & Interface Science . Nov2023:Part B, Vol. 650, p1290-1300. 11p. - Publication Year :
- 2023
-
Abstract
- Fe-MOF/FF nanorods with efficient water splitting and all-urea electrocatalytic activity were successfully synthesized by a strategy combining hydrothermal method and advanced plasma treatment technology. [Display omitted] • Fe-MOF/FF-5 were successfully fabricated through an ingenious combination of hydrothermal and plasma treatment strategies.. • Rational plasma treatment can modulate the electronic structure, electrochemical surface area of Fe-MOF/FF. • The fabricated Fe-MOF/FF-5 present efficient water splitting and overall urea electrocatalytic performance. The design of high-performance electrocatalysts for water splitting and urea oxidation reactions requires effective regulation of their electronic structure and electrochemical surface area (ECSA). In this study, we developed an in-situ grown Fe-MOF electrocatalyst on Fe foam (FF) by using a combination of easy hydrothermal synthesis and advanced plasma technology (Fe-MOF/FF). By varying the plasma treatment time, we could tailor the surface morphology and electronic structure of the Fe-MOF/FF microrods. Meanwhile, density functional theory (DFT) calculations investigated the catalytic mechanism, revealing that plasma-treated Fe-MOF/FF has a lower energy barrier for water splitting and H* adsorption during the HER process, and higher catalytic activity for UOR. Additionally, the electronic density of optimized Fe-MOF/FF is significantly expanded near the Fermi level. Remarkably, our catalysts achieved exceptional activity in both water splitting and urea electrolysis, requiring only 1.54 V and 1.472 V, respectively, at 10 mA cm−2, with excellent stability. Our findings highlight the potential of plasma technology as a powerful tool for developing multifunctional electrocatalysts for clean energy and industrial wastewater treatment applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 650
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 169922433
- Full Text :
- https://doi.org/10.1016/j.jcis.2023.07.034