Negative emissions power plant based on flexible calcium-looping process integrated with renewables and methane production.

This paper provides a review of negative carbon capture technologies. Based on these technologies, here it is proposed an innovative negative emissions power plant combining the generation and storage of energy from biomass, photovoltaic, and concentrated solar power, capturing and recovering CO 2 by producing H 2 or CH 4 as green energy carriers. The main features of the system are i) large-scale energy production system with negative CO 2 emissions; ii) 100% renewable system based on biomass and solar energy with the possibility of integrating other renewables; iii) synergistic integration of processes and systems; iv) recovery of O 2 generated by photovoltaic-driven electrolysis within the process of partial biomass oxycombustion and v) solar-driven limestone calcination. A detailed model of the entire plant is developed to evaluate the integration of the process. The model performance is assessed on an hourly basis throughout the whole year. The base case results show an energy consumption from 1 to 2.1 MJ/kg CO 2 to capture 60–77% of CO 2 emitted from the biomass plant and green methane production of more than 7500 tons/year. The negative emissions associated with the process are -612 kg CO 2 /MWh. It justifies the interest in the proposed negative emissions power plant. [Display omitted] • A synergetic integration of CO2 capture, energy storage and methane production is proposed. • A biomass power plant is considered, resulting in -612 kg CO2/MWh negative emissions. • Solar PV and CSP are integrated into the process to reduce the SPECCA to 1–2.1 kg CO2/MWh. • A large amount of solids storage is required to achieve 70–90% CO2 capture capacity. [ABSTRACT FROM AUTHOR]