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Synthesis and Properties of Calcium Alanate and Two Solvent Adducts.
- Source :
-
Inorganic Chemistry . 5/16/2005, Vol. 44 Issue 10, p3479-3484. 6p. 3 Charts, 4 Graphs. - Publication Year :
- 2005
-
Abstract
- Several ways to synthesize solvated and desolvated calcium tetrahydroaluminate by wet-chemical and mechanochemical methods are presented. The products were characterized by elemental analysis, X-ray diffraction (XRD), and infrared spectroscopy (FTIR). The crystal structure of Ca(AlH4)2·4THF was determined. After desolvation, an ultrafine powder was obtained. IR data and the mass balance suggest a compound with the composition Ca(AlH4)2, containing tetrahedral [AlH4] groups. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17105456
- Full Text :
- https://doi.org/10.1021/ic048291q