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Iron‐catalyzed oxidative [3+2] cycloaddition‐aromatization cascade: Synthesis of pyrrolo‐[2,1‐a]isoquinolines.
- Source :
-
Journal of Heterocyclic Chemistry . Sep2023, Vol. 60 Issue 9, p1633-1640. 8p. - Publication Year :
- 2023
-
Abstract
- An iron‐catalyzed approach was described for the synthesis of pyrrolo[2,1‐a]isoquinolines via oxidative [3+2] cycloaddition‐aromatization reaction using "aqueous tert‐butyl hydroperoxide (T‐HYDRO)" as an oxidant. The cascade reaction proceeds well with a broad substrate scope at room temperature in a short time and generates "desired products in moderate to high yields." [ABSTRACT FROM AUTHOR]
- Subjects :
- *ISOQUINOLINE synthesis
*ISOQUINOLINE
*OXIDIZING agents
*TEMPERATURE
Subjects
Details
- Language :
- English
- ISSN :
- 0022152X
- Volume :
- 60
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Heterocyclic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 171368987
- Full Text :
- https://doi.org/10.1002/jhet.4669