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Effect of halogenated hydrocarbon crosslinkers on self-healing poly(1,2,3-triazolium) adhesives.
- Source :
-
Polymer . Sep2023, Vol. 283, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- Poly(1,2,3-triazolium) (PTAM) is a kind of self-healing adhesive based on dynamic reversible covalent 1,2,3-triazolium, which is formed through the reaction of halogenated hydrocarbon and 1,2,3-triazole and plays an important role in the properties of PTAM. Therefore, it is valuable to understand the effect of halogenated hydrocarbon crosslinkers on the properties of PTAM. A series of PTAM adhesive with different crosslinkers have been prepared. The reactivity between halogenated hydrocarbon and 1,2,3-triazole was different. Crosslinkers with longer chain, iodine substituted and aromatic structure improved the adhesive property of PTAM adhesive joints, which was up to 17 MPa. The first self-healing efficiency of PTAM adhesive joints with aliphatic bromine crosslinkers reached more than 100% and the maximum cycle times of them was more than 9 before failure. The self-healing properties of PTAMs depend on the segment motion and anti-thermal oxygen aging of PTAMs. These results provide some insights for the structural design of self-healing adhesive and dynamic covalent materials. [Display omitted] • A series of self-healing Poly(1,2,3-triazolium) (PTAM) adhesives are obtained. • Long aliphatic, iodine-substituted and aromatic halohydrocarbon enhance adhesion. • PTAM with aliphatic bromine-substituted halohydrocarbon have better self-healing. • The first self-healing efficiency of PTAM reach more than 100%. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ADHESIVE joints
*ADHESIVES
*HALOCARBONS
*STRUCTURAL design
*BROMINE
Subjects
Details
- Language :
- English
- ISSN :
- 00323861
- Volume :
- 283
- Database :
- Academic Search Index
- Journal :
- Polymer
- Publication Type :
- Academic Journal
- Accession number :
- 171848552
- Full Text :
- https://doi.org/10.1016/j.polymer.2023.126192