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Boosting the performance in steam electrolysis of solid oxide electrolysis cell by potassium-doping in Sr2Fe1.5Mo0.5O6-δ cathode.
- Source :
-
Journal of Cleaner Production . Oct2023, Vol. 424, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- Doping potassium ions (K+) in Sr 2 Fe 1.5 Mo 0.5 O 6-δ (SFMO) double perovskite is shown to improve the electrocatalytic activity on hydrogen evolution reaction (HER) in solid oxide electrolysis cells (SOECs). The K+ dopant replaces the A-site strontium ion (Sr2+) in Sr 2 Fe 1.5 Mo 0.5 O 6-δ and causes charge imbalance that induced the formation of positively charged defects within Sr 2 Fe 1.5 Mo 0.5 O 6-δ and facilitates electrochemical processes in steam electrolysis. The enhanced processes include charge transfer, rate-determining oxide transport and surface hydrogen migration, and steam-dependent water adsorption reactions. Electrochemical impedance spectroscopy results evidently show: (1) Improvement in water adsorption reaction in K 0.15 Sr 1.85 Fe 1.5 Mo 0.5 O 6-δ (K 0.15 SFMO) due to increase oxygen vacancy concentration for steam electrolysis.(2) The polarization resistance of the cell using K 0.15 Sr 1.85 Fe 1.5 Mo 0.5 O 6-δ decreased by 50% compares to the cell using the Sr 2 Fe 1.5 Mo 0.5 O 6-δ electrode. DRT of K 0.15 SFMO revealed the oxide transport and surface hydrogen migration as the rate-determining step for steam electrolysis. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09596526
- Volume :
- 424
- Database :
- Academic Search Index
- Journal :
- Journal of Cleaner Production
- Publication Type :
- Academic Journal
- Accession number :
- 172292629
- Full Text :
- https://doi.org/10.1016/j.jclepro.2023.138747