Insights into the structural, morphological, and electronic characteristics of ZnO nanoflowers: implications for efficient photocatalytic degradation of crystal violet dye.

The present study depicts, synthesis and physicochemical investigations of zinc oxide nanoflowers (ZnO NFs). X-ray diffraction (XRD) profile of ZnO NFs revealed that ZnO NFs exhibit hexagonal wurtzite-type structure of crystallinity with P63mc space group. Microstructural analysis displays a uniform flower-like shape of ZnO NFs with petals ranging from 1 to 2 μm and an overall size of 12 µm. The absorption spectrum of ZnO NFs showed characteristic peak at 365.7 nm with an optical energy band gap of 3.40 eV. The photocatalytic activity of the ZnO NFs was evaluated by exposing crystal violet (CV) dye to UV light in the presence of the ZnO NFs. The UV–Vis spectra showed a significant decrease in the intensity of the absorbance peak at ~ 590 nm, corresponding to the degradation of the dye. The degradation followed a first-order rate equation with a rate constant of 0.0404 min−1 and excellent fit to the experimental data (R2 = 0.987). Furthermore, the ZnO NFs displayed excellent reusability, with more than 90% removal efficiency after 5 cycles. These findings demonstrate the potential of ZnO NFs as an effective photocatalyst for removing toxicity from aqueous solutions. Hall effect measurements revealed the n-type character of ZnO NFs and their resistivity, carrier concentration and Hall mobility were found to be 29 Ω cm, 7.53 × 106 cm−3, and 2.48 cm2/V s, respectively. [ABSTRACT FROM AUTHOR]