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ClO 2 -Mediated Oxidation of the TEMPO Radical: Fundamental Considerations of the Catalytic System for the Oxidation of Cellulose Fibers.
- Source :
-
Molecules . Sep2023, Vol. 28 Issue 18, p6631. 13p. - Publication Year :
- 2023
-
Abstract
- The reaction mechanism of ClO 2 -mediated TEMPO oxidation was investigated by EPR spectroscopy and UV–Vis spectroscopy in the context of an alternative TEMPO sequence for cellulose fiber oxidation. Without the presence of a cellulosic substrate, a reversibility between TEMPO and its oxidation product, TEMPO + , was displayed, with an effect of the pH and reagent molar ratios. The involvement of HOCl and Cl − , formed as byproducts in the oxidation mechanism, was also evidenced. Trapping HOCl partly inhibits the reaction, whereas adding methylglucoside, a cellulose model compound, inhibits the reversibility of the reaction to TEMPO. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 28
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 172395731
- Full Text :
- https://doi.org/10.3390/molecules28186631