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Streamlining efficient and selective synthesis of benzoxanthenones and xanthenes with dual catalysts on a single support.

Authors :
Azizi, Najmedin
Farzaneh, Fezzeh
Farhadi, Elham
Source :
Scientific Reports. 9/30/2023, Vol. 13 Issue 1, p1-12. 12p.
Publication Year :
2023

Abstract

Using two catalysts on a single support can improve reaction efficiency, higher yields, improved selectivity, and simplified reaction conditions, making it a valuable approach for industrial transformation. Herein, we describe the development of a novel and effective heterogeneous catalyst, WCl6/CuCl2, supported on graphitic carbon nitride (W/Cu@g-C3N4), which was synthesized under hydrothermal conditions. The structure and morphology properties of the W/Cu@g-C3N4 were characterized using various spectroscopic techniques, including FTIR, XRD, TEM, TGA, EDX, and SEM. The W/Cu@g-C3N4 support material enabled the rapid and efficient synthesis of benzoxanthenones and xanthenes derivatives in high yields under mild reaction conditions and short reaction times. The W/Cu@g-C3N4 catalyst was also found to be easily recyclable, and its catalytic performance did not significantly decrease after five times use. The findings suggest that W/Cu@g-C3N4 is a promising chemical synthesis catalyst with significant implications for sustainable and cost-effective organic synthesis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20452322
Volume :
13
Issue :
1
Database :
Academic Search Index
Journal :
Scientific Reports
Publication Type :
Academic Journal
Accession number :
172444035
Full Text :
https://doi.org/10.1038/s41598-023-43746-y