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Base-free regio- and stereoselective photochemical synthesis of enol ethers from 1,3-dicarbonyl compounds.
- Source :
-
Chemical Communications . 10/28/2023, Vol. 59 Issue 84, p12605-12608. 4p. - Publication Year :
- 2023
-
Abstract
- A visible light-induced kinetic controlled regioselective O-alkylation of various 1,3-dicarbonyl compounds with diazoacetates and cyclic ethers has been developed. The protocol provides a green and practical approach to highly stereoselective enol ethers under mild and base-free conditions in good to excellent yields. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ETHER synthesis
*ENOL ethers
*CYCLIC ethers
*CYCLIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 84
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 173105030
- Full Text :
- https://doi.org/10.1039/d3cc03317a