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Diffundierter Sauerstoff als dominierender flacher Akzeptor in p‐Typ Kupferiodid‐Dünnfilmen.

Authors :
Lorenz, Michael
Storm, Philipp
Gierth, Stephan
Selle, Susanne
von Wenckstern, Holger
Grundmann, Marius
Source :
Chemie Ingenieur Technik (CIT). Nov2023, Vol. 95 Issue 11, p1786-1793. 8p.
Publication Year :
2023

Abstract

The long‐term stability of the optically transparent p‐type semiconductor copper iodide is a current challenge. The electrical conductivity of CuI thin films depends critically on the environmental impact. Al2O3 cappings enhance the stability considerably. Systematic studies on Al2O3/CuI heterostructures in dependence of the N2/O2 growth pressure show the electrical conductivity of the CuI films being determined by the oxygen diffusion through Al2O3 und CuI. Oxygen seems to be a dominating acceptor in CuI. We traced the diffusion of atmospheric oxygen into CuI with 18O isotopes. [ABSTRACT FROM AUTHOR]

Details

Language :
German
ISSN :
0009286X
Volume :
95
Issue :
11
Database :
Academic Search Index
Journal :
Chemie Ingenieur Technik (CIT)
Publication Type :
Academic Journal
Accession number :
173182495
Full Text :
https://doi.org/10.1002/cite.202300007