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Laser-induced reduction and pattern regulation of graphene oxide film with high biosafety for wearable micro-supercapacitors.
- Source :
-
Journal of Alloys & Compounds . Dec2023, Vol. 969, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- A two-step laser process consisting of surface treatment and pattern scribing was developed to prepare micro-supercapacitors (MSCs) with high electrochemical performance and structural robustness. First, an ultrathin and uniform graphene oxide (GO) film was deposited onto a copper foil by electrophoretic deposition, after which a laser beam with a wavelength of 450 nm was used to remove the oxygen-containing functional groups and introduce porous structures into the GO film. Subsequently, another laser beam with a wavelength of 1064 nm was used to scribe the film to form finger-patterned electrodes. After being assembled into flexible MSCs, the volume specific capacity of the MSCs reached 1.94 F cm−3, and the power and energy densities reached 4 mW cm−3 and 0.172 mWh cm−3, respectively. After 7000 charge-discharge cycles, the device showed excellent cycling stability with a capacitance retention rate of ∼87.5%. Moreover, the MSCs could be bent into different forms with marginal capacitance loss, confirming their high structural tolerance. Remarkably, the laser-irradiated GO (L -GO) film showed high biosafety toward human empirical cells in the biotoxicity tests, indicating that the devices could be adopted as reliable micro-devices with high biosafety for fabricating wearable electronics on human skin. • Two-step laser treatment was firstly combined to prepare finger patterned flexible MSCs. • The laser treatment could both reduce the GO film and regulate the finger electrodes. • The MSCs demonstrate high energy storage performances and outstanding structural tolerance. • Toxicity tests indicate the MSCs show high biosafety on the human empirical cells. • The MSCs could serve as reliable micro-devices for wearable electronics on human skin. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 969
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 173233597
- Full Text :
- https://doi.org/10.1016/j.jallcom.2023.172285