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Formulation of KMoFe/CNTs catalyst for production of light olefins and liquid hydrocarbons via Fischer-Tropsch synthesis: Fixed-bed reactor simulation.
- Source :
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Chemical Engineering Science . Dec2023, Vol. 282, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
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Abstract
- [Display omitted] • FTS performance of promoted iron catalysts supported on CNTs were investigated. • Hydrophobicity of catalysts was compared by the water contact angle measurement. • The carburization degree of catalysts was compared by XPS and XAS spectra. • COMSOL Multiphysics was used to simulate the FTS fixed-bed reactor. Light olefins and C 5+ are strategically important products of Fischer-Tropsch synthesis (FTS) over Fe catalysts. In the present work, FTS performance of 0.5K5Mo10Fe/CNTs (DOE 2) and 2 K0.5Mo30Fe/CNTs (DOE 5) catalysts was assessed in terms of CO conversion, C 5+ selectivity, and C 2 -C 4 selectivity under industrially relevant FTS conditions (H 2 /CO = 1.0; GHSV = 2000 h−1; T = 280 ℃; P = 4.13 MPa). The C 2 -C 4 selectivity increased in DOE 2 catalyst to 51.2% with respect to DOE 5 catalyst (2.9%). Meanwhile, the selectivity toward C 5+ hydrocarbons decreased from 93.1% in DOE 5 to 8.3% for DOE 2 catalyst. DOE 5 catalyst was more hydrophobic than DOE 2 as confirmed by the water contact angle measurement, lowering CO 2 selectivity and water gas shift rate. H 2 -TPR and CO 2 -TPD indicated an increase in reducibility and basicity of DOE 5 compared with DOE 2 catalyst, which enhanced iron carbide formation and chain growth probability. The highest amount of metallic Fe in DOE 5 calcined and spent catalysts obtained by XPS and XAS spectra also suggested higher degree of carburization in DOE 5. Additionally, COMSOL Multiphysics software package was employed to provide a 2-dimensional simulation of the FTS fixed-bed reactor. Simulation results were validated using the experimental data for FTS over DOE 2 and DOE 5 catalysts. Effects of temperature on CO conversion as well as distribution of H 2 , CO, and ethylene were discussed. The simulation illustrated the effects of the fixed-bed reactor wall on both velocity and temperature profiles. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00092509
- Volume :
- 282
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Science
- Publication Type :
- Academic Journal
- Accession number :
- 173234447
- Full Text :
- https://doi.org/10.1016/j.ces.2023.119300