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Nickel-catalyzed synthesis of aryl sulfides from aromatic primary amides and thioethers via aryl exchange strategy.
- Source :
-
Journal of Organometallic Chemistry . Dec2023, Vol. 1002, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- • Aryl exchange between primary amide and thioether for aryl sulfide synthesis. • Thioether as sulfide source instead of toxic thiols. • Activation of amide through a non-decarbonylative strategy. Herein, a nickel-catalyzed synthesis of aryl sulfide through a formal aryl exchange reaction between aromatic amide and thioether was reported. This work not only realized the activation of non-activated primary amides through an unconventional dehydration strategy, but also provided a practical and facile method for aryl sulfide synthesis without odorous and toxic thiols. [Display omitted] [ABSTRACT FROM AUTHOR]
- Subjects :
- *ARAMID fibers
*AMIDES
*NICKEL sulfide
*SULFIDES
*EXCHANGE reactions
Subjects
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 1002
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 173434621
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2023.122910