Epichlorohydrin and triethylenetetramine functionalized electrosprayed Fe3O4/Chitosan magnetic microspheres for removal and separation of Congo red.

Two novel Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 magnetic microspheres with efficient dye wastewater treatment were successfully fabricated by functionalized electrosprayed Fe 3 O 4 /CS with epichlorohydrin and triethylenetetramine via a facile method. [Display omitted] • Two Fe 3 O 4 /CS-ET microspheres were fabricated via electrospraying and followed by modification. • The Q m of Congo red by Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 were 1145.42 and 617.28 mg g−1 respectively. • The adsorbent had good recyclability and reusability performance. • The mechanisms are electrostatic attraction, hydrogen interaction as well as n-π interaction. Aquatic ecosystem contaminated by organic dyes is one of the most crucial issues plaguing people worldwide, while water remediation through adsorption technology is the most sustainable option. Herein, two chitosan-based adsorbents were successfully fabricated by a facile one-step method under alkaline condition via electrospraying technology, then the above two materials were cross-linked with epichlorohydrin and grafted triethylenetetramine to prepare two kinds magnetic Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 microspheres for remediation of anion dyes namely Congo red (CR) in wastewater respectively. The morphology features, structure, composition, thermal stability, and pore diameter of the two adsorbents were acquired by SEM coupled with EDX, XRD, FTIR, TGA, and BET. The adsorption behavior of Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 microspheres towards CR from water was systematically evaluated. The determined isoelectric points (pHpzc) of Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 are orderly 7.4 and 7.8. The results confirmed that the CR remediation process can be simulated by PSO kinetic model (R 2 > 0.995) along with Langmuir isotherm (R 2 > 0.998) with maximal CR adsorption amounts by Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 microspheres of 1145.42 and 617.28 mg g−1 at pH = 7 and T = 25 °C, respectively. The negative Δ G 0, positive Δ H 0 (28.65 and 8.02 kJ mol−1), and positive Δ S 0 (112.29 and 62.71 J mol−1 K−1) signified that the adsorption of CR onto Fe 3 O 4 /CS-ET-1 and Fe 3 O 4 /CS-ET-2 microspheres surface was spontaneous and endothermic in nature. After four consecutive cycles, both magnetic microspheres remained a superior CR removal performance, indicative of the stability and recyclability of the adsorbents. [ABSTRACT FROM AUTHOR]