In situ polymerization of three-dimensional polypyrrole aerogel for efficient solar-driven interfacial evaporation and desalination.

Solar-driven interfacial evaporation (SIE) and desalination is a promising approach to mitigate the scarcity of freshwater resources. Here, a three-dimensional polypyrrole (3D PPy) aerogel was prepared by in situ polymerization of pyrrole to serve as an independent evaporator. The interconnected pore structure and super-hydrophilicity enabled PPy evaporators with rapid water transport to the top interface (< 5 s). The hydrogen interaction between polymer chains and water molecules induced large amount of intermediate water, thereby reducing the evaporation enthalpy of water in PPy aerogels. As a result, the optimized PPy aerogel attained an evaporation rate of 2.90 kg m−2 h−1 and an energy conversion efficiency of 114% under 1 sun irradiation. Moreover, the generated steam can be accelerated by the convection and an evaporation rate as high as 6.10 kg m−2 h−1 was realized at 2.5 m s−1. The rapid water transport also enabled PPy aerogel with high-efficiency of self-salt-discharge and efficient desalination for 3.5 wt% brine under 2.5 m s−1. In the outdoor SIE experiment, the excellent evaporation performance was achieved at 12:40 (7.04 kg m−2 h−1 under 74.2 mW cm−2 of solar intensity and 2.5 m s−1 of convective flow), and the cumulative evaporation of 41.50 kg m−2 for successive 9 h was obtained. After the evaporation of simulated seawater and heavy metal wastewater, the concentration of collected fresh water could be reduced about 2–3 orders of magnitude. This 3D PPy evaporation platform with high light absorption, porous structure, super-hydrophilic property, effective steam diffusion, and excellent salt resistance provides an effective way to develop advanced solar-driven water treatment technology. [Display omitted] • 3D PPy aerogel was prepared by in-situ polymerization of pyrrole. • PPy had synergy of energy conversion, porous structure, and super-hydrophilicity. • The evaporation rate was 6.1 kg m−2 h−1 under 1 sun and 2.5 m s−1 of convection. • The maximum evaporation rate was 7.04 kg m−2 h−1 in outdoor desalination system. • Efficient desalination and salt-resistance capacities of PPy aerogel were achieved. [ABSTRACT FROM AUTHOR]