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High-purity graphene and carbon nanohorns prepared by base-acid treated waste tires carbon via direct current arc plasma.
- Source :
-
Environmental Research . Dec2023:Part 1, Vol. 238, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- As the accumulation of waste tires continues to rise year by year, effectively managing and recycling these discarded materials has become an urgent global challenge. Among various potential solutions, pyrolysis stands out due to its superior environmental compatibility and remarkable efficiency in transforming waste tires into valuable products. Thus, it is considered the most potential method for disposing these tires. In this work, waste tire powder is pyrolyzed at 560 °C to yield pyrolysis carbon black, and meanwhile, the purification effects of base-acid solutions on pyrolysis carbon black are discussed. High-purity few-layer graphene flakes and carbon nanohorns are synthesized by a direct current arc plasma with H 2 and N 2 as buffer gases and high-purity pyrolysis carbon black as raw material. Under an H 2 atmosphere, hydrogen effectively terminates the suspended carbon bonds, preventing the formation of closed structures and facilitating the expansion of graphene sheets. During the preparation of carbon nanohorns, the nitrogen atoms rapidly bond with carbon atoms, forming essential C–N bonds. This nitrogen doping promotes the formation of carbon-based five-membered and seven-membered rings and makes the graphite lamellar change in the direction of towards negative curvature. Consequently, such change facilitates the formation of conical structures, ultimately yielding the coveted carbon nanohorns. This work not only provides an economical raw material for efficient large-scale synthesis of few-layer graphene and carbon nanohorns but also broadens the intrinsic worth of pyrolysis carbon black, which is beneficial to improving the recycling value of waste tires. • 99.6% purity of CBp from waste tire is achieved by using base-acid treatment. • High-purity FLG and CNHs are prepared from CBp by DC arc plasma. • FLG and CNHs prepared from CBp have good economic benefits. • H prevents growth of closed structure, facilitating growth of graphene. • N promotes growth of C5- and C7-membered rings, facilitating growth of CNHs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00139351
- Volume :
- 238
- Database :
- Academic Search Index
- Journal :
- Environmental Research
- Publication Type :
- Academic Journal
- Accession number :
- 173725731
- Full Text :
- https://doi.org/10.1016/j.envres.2023.117071