Mathematical modeling of the electrochemical phase formation through a supercooled liquid state stage.

The existence of the phenomenon of electrochemical phase formation in metals and alloys via a supercooled liquid state stage is discussed. Emergence and ultra-rapid solidification of a deeply supercooled metallic liquid represented by a multitude of liquid atomic clusters, facilitates phase transformations at the interface. A mathematical model has been obtained describing the liquid state behavior of metals and alloys being electrodeposited. The model results prove the existence of the phenomenon under discussion. [ABSTRACT FROM AUTHOR]