Recent Progress on the Synthesis and Modified Strategies of Zeolitic‐Imidazole Framework‐67 Towards Electrocatalytic Oxygen Evolution Reaction.

As a class of metal‐organic framework, the zeolitic‐imidazole framework‐67 is constructed from bridging cobalt ions and 2‐methylimidazole. The high content of abundant active cobalt species, uniform structure, ultrahigh porosity, and large surface area show the potential for multiple catalytic applications, especially electrocatalytic oxygen evolution reaction (OER). The design and synthetic strategies of catalyst‐based ZIF‐67 that approach the maximized catalytic performance are still challenging in further development. Herein, the current progress strategy on the structural design, synthetic route, and functionalization of electrocatalysts based on ZIF‐67 to boost the catalytic performance of OER is reviewed. Besides, the structurally designed catalyst from various fabricated strategies corresponding to enhancing catalytic activity is discussed. The emphasized review for understanding design and synthetic structure with catalytic performance could guide researchers in further developing catalyst‐based ZIF‐67 for improving the efficient electrocatalytic OER. [ABSTRACT FROM AUTHOR]