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Ring Expansion Reactions through Intramolecular Transamidation.
- Source :
-
European Journal of Organic Chemistry . 11/21/2023, Vol. 26 Issue 44, p1-10. 10p. - Publication Year :
- 2023
-
Abstract
- Synthetic methodologies based on cycle expansion reactions have proven to be highly effective in delivering valuable medium‐sized cycles and macrocycles. A primary method of ring expansion relies on intramolecular transamidation reactions. These reactions typically employ N‐aminoalkyl and N‐aminoacyl derivatives of lactams and their analogues as starting materials, yielding a diverse spectrum of unique nitrogen‐containing heterocycles. This Review aims to provide a comprehensive analysis of the research outcomes related to intramolecular transamidation reactions that lead to cycle expansion. This will offer the reader a perspective on the potential applications of such reactions in generating novel and intriguing types of heterocyclic systems. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LACTAM derivatives
*HETEROCYCLIC compounds
*LACTAMS
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 26
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 173823830
- Full Text :
- https://doi.org/10.1002/ejoc.202300754