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Intermolecular Carbophosphination of Alkynes with Phosphole Oxides via Ni−Al Bimetal‐Catalyzed C−P Bond Activation.
- Source :
-
Angewandte Chemie . 12/4/2023, Vol. 135 Issue 49, p1-6. 6p. - Publication Year :
- 2023
-
Abstract
- Intermolecular carbophosphination reaction of alkynes or alkenes with unreactive C−P bonds remains an elusive challenge. Herein, we used a Ni−Al bimetallic catalyst to realize an intermolecular carbophosphination reaction of alkynes with 5‐membered phosphole oxides, providing a series of 7‐membered phosphepines in up to 94 % yield. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKYNES
*BIMETALLIC catalysts
*OXIDES
*ALKENES
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 135
- Issue :
- 49
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 173849636
- Full Text :
- https://doi.org/10.1002/ange.202314701