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Colorimetric Detection of Cu2+ and Ag+ Ions Using Multi-Responsive Schiff Base Chemosensor: A Versatile Approach for Environmental Monitoring.

Authors :
Abu-Taweel, Gasem Mohammad
Al-Saidi, Hamed M.
Alshareef, Mubark
Alhamami, Mohsen A. M.
Algethami, Jari S.
Alharthi, Salman S.
Source :
Journal of Fluorescence. Nov2023, p1-16.
Publication Year :
2023

Abstract

In this study, we have synthesized a novel Schiff base-centered chemosensor, designated as <bold>SB</bold>, with the chemical name ((E)-1-(((6-methylbenzo[d]thiazol-2-yl) imino)methyl)naphthalen-2-ol). This chemosensor was structurally characterized by FT-IR, 1H NMR, UV-Vis and fluorescence spectroscopy. After structural characterization the chemosensor <bold>SB</bold> was subsequently employed for the detection of Cu2+ and Ag+, using fluorescence spectroscopy. The chemosensor <bold>SB</bold> showed excellent ability to recognize the target metal ions, leading to fluorescence enhancement and color change from yellow to yellowish orange for Cu2+ and yellow to radish for Ag+ ions. The detection capabilities of this chemosensor were impressive, showing excellent selectivity and an exceptionally low detection limit of 0.0016 µM for Cu2+ and 0.00389 µM for Ag+. Most notably, our approach enables the quantitative detection both metal ions in different water and soil samples at trace level. This achievement holds great promise for analytical applications and offers significant contributions to the field of chemical sensing and environmental protection. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10530509
Database :
Academic Search Index
Journal :
Journal of Fluorescence
Publication Type :
Academic Journal
Accession number :
173876400
Full Text :
https://doi.org/10.1007/s10895-023-03512-9