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Kinetic Delay in Cooperative Supramolecular Polymerization by Redefining the Trade‐Off Relationship between H‐Bonds and Van der Waals/π–π Stacking Interactions.
- Source :
-
Angewandte Chemie International Edition . 12/4/2023, Vol. 62 Issue 49, p1-8. 8p. - Publication Year :
- 2023
-
Abstract
- We here present how rebalancing the interplay between H‐bonds and dispersive forces (Van der Waals/π–π stacking) may induce or not the generation of kinetic metastable states. In particular, we show that extending the aromatic content and favouring the interchain VdW interactions causes a delay into the cooperative supramolecular polymerization of a new family of toluene bis‐amide derivatives by trapping the metastable inactive state. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 62
- Issue :
- 49
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 173893095
- Full Text :
- https://doi.org/10.1002/anie.202313696