Dispersion of silica nanoparticles in water/ethanol/PEG mixtures for stimuli-responsive aggregation to prepare improved fused silica glass.

The preparation of bulk-fused silica glass using stimuli-responsive silica nanoparticle (SiNP) aggregation methods is a promising research topic. For instance, the use of a SiNP/polyethylene glycol (PEG)/polyvinyl butyral (PVB) system for thermoplastic nanocomposite preparation, followed by heat-treatment sintering, has emerged as a highly precise and scalable method for obtaining fused silica glass with a short processing time. In this study, transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS), and rheological analysis were used to investigate the dispersion of SiNPs in water, ethanol, water/ethanol, and water/ethanol/PEG mixtures. Furthermore, we investigated the effect of the different solvents on regulating external stimuli in the preparation of a SiNP slurry. Our results indicate that water/ethanol mixtures have a greater ability to obtain dispersed and thin slurries than water or ethanol alone, while the inclusion of PEG can further enhance this effect.The feedstocks obtained by this method is favorable for obtaining defect-free fused silica glass. In addition, agglomerates formed by SiNPs in a liquid environment can be rearranged and partially disassembled under the action of mechanical (shear) forces. Finally, optical profilometry tests showed that the sintered fused silica glass exhibited good surface quality replication, with a roughness Sa of only 148 nm. The finding in this study provides an idea for the preparation of commercial slurry for sintering fused silica glass. [ABSTRACT FROM AUTHOR]