An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K).

Authors :: Chen, Xi-Meng
Yu, Xing-Chao
Chi, Jing-Xian
Jing, Yi
Wang, Hongju
Zhang, Na
Zhang, Chen
Ge, Yi-Wen
Chen, Xuenian
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 12/21/2023, Vol. 52 Issue 47, p17684-17688. 5p.
Publication Year :: 2023
Abstract: An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142− anion are proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13− and B10H15− intermediates were detected. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 52
Issue :: 47
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 174012919
Full Text :: https://doi.org/10.1039/d3dt03403h

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