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An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K).
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 12/21/2023, Vol. 52 Issue 47, p17684-17688. 5p. - Publication Year :
- 2023
-
Abstract
- An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142− anion are proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13− and B10H15− intermediates were detected. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 174012919
- Full Text :
- https://doi.org/10.1039/d3dt03403h