Effect of molecular weight and its modality on pressure-sensitive adhesives behavior of plant oil-based latexes.

Semibatch emulsion polymerization of high oleic soybean oil-based monomer (HO-SBM), 2–ethylhexyl acrylate (2-EHA), and styrene (St) was applied to synthesize pressure-sensitive latex adhesives with up to 40 wt% of plant oil-based content. Ternary latex copolymers with similar chemical composition and broadly different molecular weight distribution (MWD) and modality were synthesized at varying temperatures and the mechanism of free-radical initiation. Conventional thermal initiation with ammonium persulphate at 80 °C and ascorbic acid/ tert -butyl hydroperoxide redox system of lower reaction temperature up to 20 °C were employed. Linear, short-chain, and long-chain branched macromolecules are formed due to chain-breaking reactions of HO-SBM (chain transfer on allyl groups) and 2-EHA (inter- and intramolecular chain transfer on the polymer). The dominant effect of chain transfer on allyl group protons and subsequent decrease in molecular weight was observed at higher reaction temperatures, while extensively branched polymer with high molecular weight was obtained at reaction temperature close to 20 °C. The effect of MWD and branching on the PSAs performance of synthesized biobased latexes was studied using loop tack and peel strength and lap shear testing and compared to two commercial PSA tapes as a benchmark. A significant increase in shear strength (up to 0.23 MPa) was observed for latex adhesives due to high molecular weight fractions, maintaining satisfactory level of tack (3–7 N) and peel (3–6 N/in). Broad MWD of the copolymers can be beneficial for providing materials with high shear strength (0.25–0.33 MPA) while preserving the significant level of tack (2–4 N) and peel strength (9–12 N/in) on both glass and steel substrates. [ABSTRACT FROM AUTHOR]